Andrea Steinhaus

andrea.steinhaus@uni-due.de
NETZ Room 4.11
+49 203 / 379-8219
2016 | HeinrichHeine-University Düsseldorf
Chemistry, Master of Science “Synthesis of ferrocene-substituted oligoenes
2013 | Heinrich-Heine-University Düsseldorf
Chemistry, Bachelor of Science “Chiral recognition of linear and linked polymers by cyclodextrins

08/2016 – 04/2017 | Project Leader (freelancer) at the German Red Cross (DRK)
– Create and maintain in projects in the field of refugee aid
– Maintain communication of permanent employees, volunteers and refugees
09/2016 – 01/2017 | Internship at the LG Technology Center Europe in Ratingen
– Scouting new technologies in the area of next generation energy storage solutions
– Generate technology studies and surveys
– Managing requests of the South Korean team
02 – 08/2016 | Internship at ASK Chemicals GmbH in Hilden
– Synthesis optimization of resole CO2 resins
– Performance of sand analytical processes
– Presentation of results and evaluation of the product within the team
– Exercising design of experiments (DOE)
Since 2015 | German Red Cross (DRK)
– Voluntary service in the field of refugee aid

PhD TopicSelf-Assembly in 3D Confinement for the synthesis of Janus nanostructures

The self-assembly of block copolymers in spherical confinement has become a versatile route to generate microparticles with unusual and frustrated morphologies. To date, AB diblock copolymers have been the centre of investigation with studies on ABC triblock terpolymers being almost non-existent, despite their larger and more complex phase behaviour. The formation of an axially stacked lamella-ring (lr) morphology through confinement assembly of ABC triblock terpolymers in drying nanoemulsion droplets. This morphology consists of a concentric arrangement of B-rings sandwiched between axially stacked lamellae of A and C. Cross-linking of the B-rings locks the toroidal shape and Janus nanorings (JNRs) are obtained with two strictly separated brushes of A and C on top and bottom of the ring. The process can be extended to a variety of triblock terpolymers with different chemistry and block ratios to design multicompartment microparticles, patchy particles, and topological nanoparticles.

Publication

1) Andrea Steinhaus, Deepika Srivastva, Arash Nikoubashman*, André H. Gröschel*, Janus nanostructures from ABC/B triblock terpolymer blends, Polymers, 2019, accepted.
2) Andrea Steinhaus, Ramzi Chakroun, Markus Müllner, Tai-Lam Nghiem, Marcus Hildebrandt, André H. Gröschel*, Confinement assembly of triblock terpolymers for the synthesis of Janus nanoringsACS Nano, 2019, 13, 6269-6278.
DOI: 10.1021/acsnano.8b09546
3) Xiaolian Qiang, Andrea Steinhaus, Chen Chen, Ramzi Chakroun, André H. Gröschel*, Template‐free synthesis and selective filling of Janus nanocups, Angew. Chem. Int. Ed. 2019, 58, 21, 7122-7126.
DOI: 10.1002/anie.201814014
4) Tai-Lam Nghiem, Andrea Steinhaus, Ramzi Chakroun, Stefanie Tjaberings, Xiaolian Qiang, Chen Chen, Alexander Tjaberings, Giada Quintieri, and André H. Gröschel, Self-Assembly of Soft Nanoparticles (Book Chapter), 2018.
DOI: 10.1016/B978-0-12-803581-8.10449-7
5) Andrea Steinhaus, Théophile Pelras, Ramzi Chakroun, André H. Gröschel,* and Markus Müllner*, Self-Assembly of Diblock Molecular Polymer Brushes in the Spherical Confinement of Nanoemulsion Droplets, Macromol. Rapid Commun. 2018, 39, 1800177.
DOI: 10.1002/marc.201800177

Research Stay

04-05/2019 | Dr. Markus Müllner Research Group (The University of Sydney, Australia)
DAAD – Australia-Germany Joint Research Co-Operation
Topic: Biocompatible, ring-shaped nanoparticles and their potential as a new type of polymer nanomedicines

Presentations
09/2019 | Particle Based Materials Symposium in Ulm, TalkBlock Copolymers in 3D Confinement: Janus Structures with Complex Topology
08/2019 | Bayreuth Polymer Symposium in Bayreuth, Poster PresentationBlock Copolymers in 3D Confinement: Janus Structures with Complex Topology
08/2019 | ACS National Meeting and Expo (San Diego, USA), TalkBlock Copolymers in 3D Confinement: Janus Structures with Complex Topology
11/2018 | CENIDE Anniversary Celebration in Essen, Poster PresentationTopological evolution of complex polymer nanostructures as templates for hybrid material
11/2018 | 2nd Materials Chain International Conference in Bochum, Poster PresentationTopological  evolution of complex polymer nanostructures as templates for hybrid material
02/2018 | Macromolecular Colloquium in Freiburg, Poster Presentation
Janus Nanostructures with Complex Topology: Triblock Terpolymer Multicompartment Microparticles
05/2017 | Workshop: Research of Evonik Scholars
Shanghai Jiao Tong University and Duisburg-Essen University

Participations
11/2018 | ScienceNight Ruhr 2018 @UDE
10/2017 | 4th Ruhr Symposium @UDE

Supervision of Students
2017 | Ramzi Chakroun, Master’s Thesis
Mikrophasenseparation von ABC Triblock Terpolymeren in Nanoemulsionströpfchen
2017 | Suna Azdhari, Bachelor’s Thesis
Synthese und Phasenverhalten von Polystyrolsulfonsäure Blockcopolymeren

Supervision of Lab Courses
05/2018 | Univeristy of Duisburg-Essen
Supervision of the academic lab course „Physikalische Chemie B.SC. Water Science“
01 02/ 2016 | Heinrich-Heine-University
Supervision of the academic lab course „Fortgeschrittene Physikalische Chemie“
06/2015 | Heinrich-Heine-University
Supervision of the academic lab course „Grundlagen der Physikalischen Chemie“

Other Links
Faculty of Chemistry @UDE
Highlight of the Month July 2019
Accepted Inside Cover @ACS Nano
Press Release CENIDE @UDE
Publication in Angewandte Chemie Int. Ed.
Accepted Back Cover @MCR